Development of a phenolic resin production strategy aligned with market needs in Ecuador
DOI:
https://doi.org/10.26423/rctu.v11i1.757Keywords:
simulation, phenolic resin, process designAbstract
The objective of this study was to develop a strategy for designing a phenolic resin (floral foam) production plant to meet the existing demand in the country, using the PRO II simulation software. For this purpose, the design needs were identified through block diagrams (BDF) and process flow diagrams (PFD), considering the involved unit operations. Additionally, a batch reactor was presented, designed to achieve high conversion in the production of floral foam, according to the reaction for obtaining resol-type floral foam. For this, the volume value was considered, as well as the optimal operating conditions, including pressure and temperature, through a sensitivity analysis. The results were verified by calculating mass and energy balances, using the demand for floral foam, which was approximately 143 tons annually, obtained from the National Customs Service of Ecuador (Importations) website. This value was used for the calculation of daily production and helped to demonstrate the validity of the simulation. The simulated value was 63.4552 kg/day, compared to the calculated phenolic resin production value of 63.3547 kg/day. This shows the relevance of the study and encourages the generation of research that benefits the creation and development of the petrochemical industry.
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COVARRUBIAS VELÁZQUEZ, H.E.; SÁENZ GALINDO, Aidé and CASTAÑEDA FACIO, Adali O. Resinas Termoestables De Fenol-Formaldehído. Rev. Iberoam. Polímeros, vol. 17, no. 6, pp. 266–276, 2016. Available: https://eviberpol.org/wp-content/uploads/2019/07/2016-covarrubias.pdf
ASIM, Mohammad; Saba, Naheed.; JAWAID, Mohammad; Nasir, Mohammed; Pervaiz, Mohammed and ALOTHMAN, Othlam. A Review on Phenolic Resin and its Composites. Curr Anal Chem, vol. 14, no. 3, pp. 185–197, May 2018. DOI: https://doi.org/10.2174/1573411013666171003154410 DOI: https://doi.org/10.2174/1573411013666171003154410
LEE, Seung-Hang; TERAMOTO, Yoshikuni and SHIRAISHI, Nobuo. Resol‐type phenolic resin from liquefied phenolated wood and its application to phenolic foam. J Appl Polym Sci, vol. 84, no. 3, pp. 468–472, Apr. 2002. DOI: https://doi.org/10.1002/app.10018 DOI: https://doi.org/10.1002/app.10018
VENEGAS SEGURA, Silvia; DOMÍNGUEZ PATIÑO, Martha and VARGAS ORTEGA, Joel. Elaboración y caracterización de una espuma para el desarrollo e implementación de un procesos sustentable. Universidad Autónoma del Estado de Morelos. 2019. Available: http://riaa.uaem.mx/handle/20.500.12055/3138
TANG, Kaihong; ZHANG, Ailing; GE, Tiejun; LIU, Xiaofeng; TANG, Xiaojun and LI, Yongjiang. Research progress on modification of phenolic resin. Mater Today Commun, vol. 26, p. 101879, Mar. 2021. DOI: https://doi.org/10.3390/polym15173543
GONG, X; MENG, Y; LU, J; TAO, Y; Cheng, Y. and WANG, H. A Review on Lignin‐Based Phenolic Resin Adhesive. Macromol Chem Phys, vol. 223, no. 4, Feb. 2022. DOI: https://doi.org/10.1002/macp.202100434 DOI: https://doi.org/10.1002/macp.202100434
SALTHAMMER, Tunga; MENTESE, Sibel and MARUTZKY, Rainer. Formaldehyde in the Indoor Environment. Chem Rev, vol. 110, no. 4, pp. 2536–2572, Apr. 2010. DOI: https://doi.org/10.1021/cr800399g DOI: https://doi.org/10.1021/cr800399g
ALLEN, D.J. and ISHIDA, H. Thermosets: Phenolics, Novolacs, and Benzoxazine. Encyclopedia of Materials: Science and Technology, Elsevier, 2001, pp. 9226–9229. DOI: https://doi.org/10.1016/B0-08-043152-6/01662-4
BERDNIKOVA, Polina; ZHIZHINA, E.G. and PAI, Z.P. Phenol-Formaldehyde Resins: Properties, Fields of Application, and Methods of Synthesis. Catal Ind, vol. 13, no. 2, pp. 119–124, Apr. 2021. DOI: https://doi.org/10.1134/S2070050421020033
ALLEN, D.J. and ISHIDA, H. Thermosets: Phenolics, Novolacs, and Benzoxazine. Encyclopedia of Materials: Science and Technology, Elsevier, 2001, pp. 9226–9229. DOI: https://doi.org/10.1016/B0-08-043152-6/01662-4 DOI: https://doi.org/10.1016/B0-08-043152-6/01662-4
FROLLINI, E.; Silva, C.G. and RAMIRES, E.C. Phenolic resins as a matrix material in advanced fiber-reinforced polymer (FRP) composites. Advanced Fibre-Reinforced Polymer (FRP) Composites for Structural Applications, Elsevier, 2013, pp. 7–43. DOI: https://doi.org/10.1533/9780857098641.1.7 DOI: https://doi.org/10.1533/9780857098641.1.7
LI, Bing; YUAN, Zhongshun; SCHMIDT, John and XU, Chunbao (Charles). “New foaming formulations for production of bio-phenol formaldehyde foams using raw kraft lignin. Eur Polym J, vol. 111, pp. 1–10, Feb. 2019. DOI: https://doi.org/10.1016/j.eurpolymj.2018.12.011 DOI: https://doi.org/10.1016/j.eurpolymj.2018.12.011
AHMAD, Iftikhar; DOLE, John M.; CLARK, Erin M. R. and BLAZICH, Frank A. Floral foam and/or conventional or organic preservatives affect the vase-life and quality of cut rose ( Rosa × hybrida L.) stems. J Hortic Sci Biotechnol, vol. 89, no. 1, pp. 41–46, Jan. 2014. DOI: https://doi.org/10.1080/14620316.2014.11513046 DOI: https://doi.org/10.1080/14620316.2014.11513046
XU, Jie; BRODU, Nicolas; DEVOUGUE-BOYER, Christine; YOUSSEF, Boulos and TAOUK, Bechara. Biobased novolac resins cured with DGEBA using water-insoluble fraction of pyrolysis bio-oil: Synthesis and characterization. J Taiwan Inst Chem Eng, vol. 138, p. 104464, Sep. 2022, DOI: https://doi.org/10.1016/j.jtice.2022.104464 DOI: https://doi.org/10.1016/j.jtice.2022.104464
HIRAI, Takayuki; YAGI, Kenichi; OKAMOTO, Kazuo; ONOCHI, Yusaku and KAWADA, Jumpei. In Situ Reactive Compatibilization of Polyamide 6 and Polycarbonate Blend by the Catalytic Effect of Phenol Novolac. Ind Eng Chem Res, vol. 59, no. 5, pp. 1855–1861, Feb. 2020, DOI: https://doi.org/10.1021/acs.iecr.9b05970. DOI: https://doi.org/10.1021/acs.iecr.9b05970
A. Pizzi and C. C. Ibeh. Phenol–Formaldehydes. Handbook of Thermoset Plastics, Elsevier, 2014, pp. 13–44. DOI: https://doi.org/10.1016/B978-1-4557-3107-7.00002-6 DOI: https://doi.org/10.1016/B978-1-4557-3107-7.00002-6
ATIEMO‐OBENG, Victor A. and CALABRESE, Richard V. Rotor–Stator Mixing Devices. Handbook of Industrial Mixing, Wiley, 2003, pp. 479–505. DOI: https://doi.org/10.1002/0471451452.ch8 DOI: https://doi.org/10.1002/0471451452.ch8
L. Yuandan. Wet Floral Foam Making Machine Flower Mud Production Line Complete Floral Foam Making Production Line. alibaba. [Online]. Available: https://www.alibaba.com/product-detail/Wet-Floral-Foam-Making-Machine-Flower_1601117148148.html?module=company
YU, Yuxiang; WANG, Yufie; XU, Pingping and CHANG, Jianmin. Preparation and Characterization of Phenolic Foam Modified with Bio-Oil. Materials, vol. 11, no. 11, p. 2228, Nov. 2018, DOI: https://doi.org/10.3390/ma11112228 DOI: https://doi.org/10.3390/ma11112228
Servicio Nacional de Aduana del Ecuador, No Title.[Online]. Available: https://www.aduana.gob.ec/importaciones/
GARDZIELLA, Arno; PILATO, Louis A. and KNOP, Andre. Phenolic Resins: Chemistry, Reactions, Mechanism. Phenolic Resins. Springer, Berlin, Heidelberg. 1985. DOI: https://doi.org/10.1007/978-3-662-04101-7_2 DOI: https://doi.org/10.1007/978-3-662-04101-7_2
BERDNIKOVA, P.V.; ZHIZHINA, E.G. and PAI, Z.P. Phenol-Formaldehyde Resins: Properties, Fields of Application, and Methods of Synthesis. Catal Ind, vol. 13, no. 2, pp. 119–124, Apr. 2021. DOI: https://doi.org/10.1134/S2070050421020033 DOI: https://doi.org/10.1134/S2070050421020033
LANDROCK, A. H. Handbook_of_Plastic_Foams, vol. 1. Elsevier Science, 1995. Available: https://www.sciencedirect.com/book/9780815513575/handbook-of-plastic-foams#book-description
Yang, Chane-Yuan; TSAI, Ding-Chi and Chien, Yu-Shu. The strategy developed for high conversion and the multiplicity problems of biochemical reaction in a real CSTR with Cholette’s model. International Journal of Chemical Reactor Engineering, vol. 19, no. 12, pp. 1245–1270, Dec. 2021. DOI: https://doi.org/10.1515/ijcre-2021-0016 DOI: https://doi.org/10.1515/ijcre-2021-0016
CREMER‐BUJARA, Esther; BIESSEY, Philip and GRÜNEWALD, Marcus. Simulation of Polymer Reactors Using the Compartment Modeling Approach. Macromol React Eng, vol. 14, no. 1, Feb. 2020, DOI: https://doi.org/10.1002/mren.201900034 DOI: https://doi.org/10.1002/mren.201900034
DAGDE, Kekpugile Kenneth; AKPA, Gunorubon Jackson; OSAROWORLU, Obarijimah and ADELOYE, Olalekan Michael. Simulation of continuous stirred tank reactor (CSTR) for polypropylene production. Global Journal of Engineering and Technology Advances, vol. 5, no. 2, pp. 014–023, Nov. 2020. DOI: https://doi.org/10.30574/gjeta.2020.5.2.0095 DOI: https://doi.org/10.30574/gjeta.2020.5.2.0095
LI, Shaofan. Computational and Experimental Simulations in Engineering, vol. 143. in Mechanisms and Machine Science, vol. 143. Cham: Springer International Publishing, 2024. DOI: https://doi.org/10.1007/978-3-031-42515-8. DOI: https://doi.org/10.1007/978-3-031-42515-8
GRANADO, Lérys; TAVERNIER, Romain; FOYER, Gabriel; DAVID, Ghislain and CAILLOL, Sylvain. Comparative curing kinetics study of high char yield formaldehyde- and terephthalaldehyde-phenolic thermosets. Thermochim Acta, vol. 667, pp. 42–49, Sep. 2018, DOI: https://doi.org/10.1016/j.tca.2018.06.013. DOI: https://doi.org/10.1016/j.tca.2018.06.013
PIZZI, A and IBEH, C.C. Phenol-formaldehyde resins. Handbook of Thermoset Plastics, Elsevier, 2022, pp. 13–40. DOI: https://doi.org/10.1016/B978-0-12-821632-3.00013-0 DOI: https://doi.org/10.1016/B978-0-12-821632-3.00013-0
DURÁN-GARCÍA, Martin Enrique and RUIZ-NAVAS, Ricardo Alejandro. Simulador de propiedades termodinámicas en la conversión de la biomasa forestal de aserrín de pino. Maderas. Ciencia y tecnología, no. ahead, pp. 0–0, 2020. DOI: http://dx.doi.org/10.4067/S0718-221X2020005000309. DOI: https://doi.org/10.4067/S0718-221X2020005000309
GIL CHAVES, Iván Darío; GUEVARA LÓPEZ, Javier Ricardo; GARCÍA ZAPATA, José Luis; LEGUIZAMÓN ROBAYO, Alexander and RODRÍGUEZ NIÑO, Gerardo. Process Analysis and Simulation in Chemical Engineering. Cham: Springer International Publishing, 2016. Available: https://link.springer.com/book/10.1007/978-3-319-14812-0 DOI: https://doi.org/10.1007/978-3-319-14812-0
MONNI, Janne; ALVILA, Leila; RAINIO, Jouni and PAKKANEN, Tuula T. Novel two‐stage phenol–formaldehyde resol resin synthesis. J Appl Polym Sci, vol. 103, no. 1, pp. 371–379, Jan. 2007. DOI: https://doi.org/10.1002/app.24615 DOI: https://doi.org/10.1002/app.24615
LIANG, Bingchuan; LI, Xiangyu; HU, Lihong; BO, Caiying; ZHOU, Jing and ZHOU, Yonghong. Foaming resol resin modified with polyhydroxylated cardanol and its application to phenolic foams. Ind Crops Prod, vol. 80, pp. 194–196, Feb. 2016, DOI: https://doi.org/10.1016/j.indcrop.2015.11.087 DOI: https://doi.org/10.1016/j.indcrop.2015.11.087
PERMINOVA, Daria A.; MALKOV, Viktor S.; GUSСHIN, Viktor and EISENREICH, Norbert. Influence of glyoxal on curing of urea-formaldehyde resins. Int J Adhes Adhes, vol. 92, pp. 1–6, Jul. 2019, DOI: https://doi.org/10.1016/j.ijadhadh.2019.04.001 DOI: https://doi.org/10.1016/j.ijadhadh.2019.04.001
TANG, Kaihong; ZHANG, Ailing; GE, Tiejun; LIU, Xiaofeng; TANG, Xiaojun and LI, Yonjiang. Research progress on modification of phenolic resin. Mater Today Commun, vol. 26, p. 101879, Mar. 2021, DOI: https://doi.org/10.1016/j.mtcomm.2020.101879 DOI: https://doi.org/10.1016/j.mtcomm.2020.101879
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